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BREAKTHROUGH SOLAR CELL PRODUCES BURNABLE FUEL FROM CO2 AND SUNLIGHT

02-08-2016
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Scientists at the University of Illinois at Chicago have developed a solar cell that cheaply and efficiently converts atmospheric carbon dioxide directly into usable hydrocarbon fuel, using only sunlight for energy.

The traditional solar cells converts sunlight into electricity that is stored in heavy batteries. The new device essentially does the work of plants, converting atmospheric carbon dioxide into fuel, solving two crucial problems at once.

A solar farm of such “artificial leaves” could remove significant amounts of carbon from the atmosphere and produce energy-dense fuel efficiently.

“The new solar cell is not photovoltaic — it’s photosynthetic,” says Amin Salehi-Khojin, assistant professor of mechanical and industrial engineering at UIC and senior author on the study.

“Instead of producing energy in an unsustainable one-way route from fossil fuels to greenhouse gas, we can now reverse the process and recycle atmospheric carbon into fuel using sunlight,” he said.

Engineers have been exploring different catalysts to drive CO2 reduction, but so far such reactions have been inefficient and rely on expensive precious metals such as silver, Salehi-Khojin said.

“What we needed was a new family of chemicals with extraordinary properties,” he said.

Salehi-Khojin and his team focused on a family of nano-structured compounds called transition metal dichalcogenides — or TMDCs — as catalysts, pairing them with an unconventional ionic liquid as the electrolyte inside a two-compartment, three-electrode electrochemical cell.

The best of several catalysts they studied turned out to be nanoflake tungsten diselenide.

“The new catalyst is more active; more able to break carbon dioxide’s chemical bonds,” said UIC postdoctoral researcher Mohammad Asadi, first author on the Science paper.

The new catalyst is 1,000 times faster than noble-metal catalysts — and about 20 times cheaper.

“The active sites of the catalyst get poisoned and oxidized,” Salehi-Khojin said. The breakthrough, he said, was to use an ionic fluid called ethyl-methyl-imidazolium tetrafluoroborate, mixed 50-50 with water.

“The combination of water and the ionic liquid makes a co-catalyst that preserves the catalyst’s active sites under the harsh reduction reaction conditions,” Salehi-Khojin said.

The UIC artificial leaf consists of two silicon triple-junction photovoltaic cells of 18 square centimeters to harvest light; the tungsten diselenide and ionic liquid co-catalyst system on the cathode side; and cobalt oxide in potassium phosphate electrolyte on the anode side.

The technology should be adaptable not only to large-scale use, like solar farms, but also to small-scale applications, Salehi-Khojin said. In the future, he said, it may prove useful on Mars, whose atmosphere is mostly carbon dioxide, if the planet is also found to have water.

“This work has benefitted from the significant history of NSF support for basic research that feeds directly into valuable technologies and engineering achievements,” said NSF program director Robert McCabe.

“The results nicely meld experimental and computational studies to obtain new insight into the unique electronic properties of transition metal dichalcogenides,” McCabe said. 

“The research team has combined this mechanistic insight with some clever electrochemical engineering to make significant progress in one of the grand-challenge areas of catalysis as related to energy conversion and the environment.”

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